核級拋光樹脂的制成與水處理影響-天津市津達正通環(huán)?？萍加邢薰?/title> <link href="/skins/387392/css/css.css" rel="stylesheet" type="text/css"> <script type="text/javascript" src="/skins/387392/js/jquery.pack.js"></script> <script type="text/javascript" src="/skins/387392/js/jquery.SuperSlide.js"></script> <script type="application/ld+json"> { "@context": "https://ziyuan.baidu.com/contexts/cambrian.jsonld", "@id": "http://www.klkli.cn/Article-3810813.html", "title": "核級拋光樹脂的制成與水處理影響", "pubDate": "2024-09-17T21:32:15", "upDate": "2024-09-17T21:32:15" }</script> <script language="javaScript" src="/js/JSChat.js"></script><script language="javaScript">function ChatBoxClickGXH() { DoChatBoxClickGXH('https://chat.chem17.com',390069) }</script><script>!window.jQuery && document.write('<script src="https://public.mtnets.com/Plugins/jQuery/2.2.4/jquery-2.2.4.min.js">'+'</scr'+'ipt>');</script><script type="text/javascript" src="https://chat.chem17.com/chat/KFCenterBox/387392"></script><script type="text/javascript" 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joinstyle="miter"></v:stroke><v:formulas><v:f eqn="if lineDrawn pixelLineWidth 0"></v:f><v:f eqn="sum @0 1 0"></v:f><v:f eqn="sum 0 0 @1"></v:f><v:f eqn="prod @2 1 2"></v:f><v:f eqn="prod @3 21600 pixelWidth"></v:f><v:f eqn="prod @3 21600 pixelHeight"></v:f><v:f eqn="sum @0 0 1"></v:f><v:f eqn="prod @6 1 2"></v:f><v:f eqn="prod @7 21600 pixelWidth"></v:f><v:f eqn="sum @8 21600 0"></v:f><v:f eqn="prod @7 21600 pixelHeight"></v:f><v:f eqn="sum @10 21600 0"></v:f></v:formulas><v:path o:connecttype="rect" gradientshapeok="t" o:extrusionok="f"></v:path><o:lock aspectratio="t" v:ext="edit"></o:lock><v:fill o:detectmouseclick="t"></v:fill></span></p><p style="MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan; mso-line-height-alt: 1.15pt"><span style="FONT-SIZE: 15pt; FONT-FAMILY: 黑體; COLOR: red; mso-bidi-font-family: 黑體">我公司生產(chǎn)的拋光樹脂分為<span lang="EN-US">18</span>兆和<span lang="EN-US">15</span>兆的一箱<span lang="EN-US">5</span>包，一包<st1:chmetcnv w:st="on" tcsc="0" numbertype="1" negative="False" hasspace="False" sourcevalue="5" unitname="升"><span lang="EN-US">5</span>升</st1:chmetcnv>！可根據(jù)客戶來訂做包裝（桶裝，編織袋裝）</span><span lang="EN-US" style="FONT-SIZE: 15pt; FONT-FAMILY: "hiragino sans gb"; COLOR: red; mso-fareast-font-family: "hiragino sans gb"; mso-bidi-font-family: "hiragino sans gb""><o:p></o:p></span></p><p style="MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan; mso-line-height-alt: 1.15pt"><span style="FONT-SIZE: 15pt; FONT-FAMILY: 黑體; COLOR: red; mso-bidi-font-family: 黑體">專業(yè)生產(chǎn)銷售超純水樹脂，主要用于<span lang="EN-US">DI</span>水、超純水系統(tǒng)的后置精混床，即核子級混床所用，保證優(yōu)質(zhì)低價。拋光樹脂當(dāng)進水在<span lang="EN-US">5</span>μ<span lang="EN-US">s/cm</span>，出水水質(zhì)電阻≥<st1:chmetcnv w:st="on" tcsc="0" numbertype="1" negative="False" hasspace="False" sourcevalue="15" unitname="m"><span lang="EN-US">15M</span></st1:chmetcnv>Ω<span lang="EN-US">/cm<st1:chmetcnv w:st="on" tcsc="0" numbertype="1" negative="True" hasspace="False" sourcevalue="18" unitname="m">-18M</st1:chmetcnv></span>Ω<span lang="EN-US">/cm.</span></span><span lang="EN-US" style="FONT-SIZE: 15pt; FONT-FAMILY: "hiragino sans gb"; COLOR: red; mso-fareast-font-family: "hiragino sans gb"; mso-bidi-font-family: "hiragino sans gb""><o:p></o:p></span></p><p style="MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan; mso-line-height-alt: 1.15pt"><span style="FONT-SIZE: 15pt; FONT-FAMILY: 黑體; COLOR: red; mso-bidi-font-family: 黑體">注：拋光樹脂是陰陽離子樹脂混合在一起的，我們出廠就以按比例混合好了，客戶直接裝填使用就可以，無需再生，使用起來方便，快捷，效果好！</span><span lang="EN-US" style="FONT-SIZE: 15pt; FONT-FAMILY: "hiragino sans gb"; COLOR: red; mso-fareast-font-family: "hiragino sans gb"; mso-bidi-font-family: "hiragino sans gb""><o:p></o:p></span></p><p class="MsoNormal"><span lang="EN-US"><o:p> </o:p></span></p><p class="MsoNormal"><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">拋光混床樹脂是再生型高轉(zhuǎn)型率陽陰混合樹脂，陽樹脂為</span><span lang="EN-US">H</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">型，陰樹脂為</span><span lang="EN-US">OH</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">型，此時陽、陰樹脂因正負(fù)電荷的作用力而抱團在一起，形成無數(shù)級復(fù)床，水流通過混床樹脂后經(jīng)過無數(shù)級的交換過濾，值得高純度的水質(zhì)。陽樹脂的</span><span lang="EN-US">H+</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">離子與水中的</span><span lang="EN-US">Ca2+</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">、</span><span lang="EN-US">Mg2+</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">、</span><span lang="EN-US">Na+</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">等陽離子發(fā)生置換反應(yīng)，陰樹脂的</span><span lang="EN-US">OH-</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">與水中硫酸根，氯根等陰離子發(fā)生置換反應(yīng)，陽樹脂置換出的</span><span lang="EN-US">H+</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">與陰離子置換出的</span><span lang="EN-US">OH-</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">離子結(jié)合形成</span><span lang="EN-US">H2O</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">。但隨著使用時間的延長，樹脂的交換能力會逐漸下降（也即</span><span lang="EN-US">H+</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">和</span><span lang="EN-US">OH-</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">逐漸被相應(yīng)離子所交換），陽陰樹脂之間的靜電也會減弱，終樹脂失效后導(dǎo)致分層。</span></p><p class="MsoNormal"><span lang="EN-US"> </span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">另外分層的原因還有使用與裝填過程中的一些不合理工藝引起，比如樹脂裝天前，在罐體內(nèi)加入過多水，導(dǎo)致混合樹脂分層；比如混合樹脂在使用過層中，停停用用導(dǎo)致水流反沖（反沖類似于對混合樹脂的反洗）導(dǎo)致混合樹脂分層等多種原因都會引起分層情況的發(fā)生。</span></p><p class="MsoNormal"><span lang="EN-US"> </span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">混合樹脂分層后，無數(shù)級的復(fù)床也即不存在，比重較輕的陰樹脂會在上層，比重較大的陽樹脂會往下沉，這個時候由于離子交換的不同步，會導(dǎo)致混床樹脂出水不合格，周期制水量也受到較大影響。</span></p><p class="MsoNormal"><span lang="EN-US"><o:p> </o:p></span></p><p class="MsoNormal"><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">目前國內(nèi)高、超純水用戶對此產(chǎn)品的應(yīng)用不是很了解，所以普遍存在盲目追崇昂貴的進口拋光混床樹脂，而國內(nèi)部分小樹脂生產(chǎn)企業(yè)，為了獲得，以不合格的低價的產(chǎn)品參與市場惡性低價競爭，也導(dǎo)致了部分用戶對國產(chǎn)拋光樹脂的不認(rèn)可，希望通過交流，讓廣大終端用戶了解產(chǎn)品的理化性能和應(yīng)用方法。</span></p><p class="MsoNormal"><span lang="EN-US"><span style="mso-spacerun: yes"> </span></span></p><p class="MsoNormal"><span lang="EN-US"><span style="mso-spacerun: yes"> </span></span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">拋光樹脂產(chǎn)品使用及注意事項</span></p><p class="MsoNormal"><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">　　</span><span lang="EN-US">1.</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">拋光樹脂</span><span lang="EN-US">(</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">是由高度純化、轉(zhuǎn)型的</span><span lang="EN-US">H</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">型陽樹脂和</span><span lang="EN-US">OH</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">型陰樹脂預(yù)混合而成，如果裝填和操作得當(dāng)，在初的周期中即可制備出電阻率大于</span><st1:chmetcnv w:st="on" tcsc="0" numbertype="1" negative="False" hasspace="False" sourcevalue="18" unitname="m"><span lang="EN-US">18.0M</span></st1:chmetcnv><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">Ω</span><span lang="EN-US">.cm</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">和</span><span lang="EN-US">TOC</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">小于</span><span lang="EN-US">10ppb</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">的超純水。</span></p><p class="MsoNormal"><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">　　</span><span lang="EN-US">2.</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">樹脂開封后長時間暴露在空氣中會吸收二氧化碳，因此拆包需盡快使用。不使用部分須小心密封，存放于避光陰涼處，環(huán)境溫度以</span><span lang="EN-US">5<st1:chmetcnv w:st="on" tcsc="0" numbertype="1" negative="True" hasspace="False" sourcevalue="40" unitname="℃">-40<span lang="EN-US" style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri"><span lang="EN-US">℃</span></span></st1:chmetcnv><span lang="EN-US" style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">為宜。</span></span></p><p class="MsoNormal"><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">　　</span><span lang="EN-US">3.</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">在運輸、儲存和裝填過程中，任何無機或有機物質(zhì)的接觸都會使樹脂受到污染，從而降低出水水質(zhì)</span><span lang="EN-US">;</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">影響運行工況。因此必須保證所有用于裝填、操作的設(shè)備和水不會污染樹脂。所有與樹脂接觸的水都必須使用高純水</span><span lang="EN-US">(</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">本文中所涉及到的水均指</span><span lang="EN-US">"</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">高純水</span><span lang="EN-US">"</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">，即電阻率大于等于</span><st1:chmetcnv w:st="on" tcsc="0" numbertype="1" negative="False" hasspace="False" sourcevalue="10" unitname="m"><span lang="EN-US">10M</span></st1:chmetcnv><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">Ω</span><span lang="EN-US">.cm</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">，同時</span><span lang="EN-US">TOC</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">盡可能低于</span><span lang="EN-US">30ppb</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">的水</span><span lang="EN-US">)</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">，所有接觸樹脂的設(shè)備或器具都要在使用前經(jīng)過高純水清洗。</span></p><p class="MsoNormal"><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">　　</span><span lang="EN-US">4.</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">如為換裝樹脂，設(shè)備中原有的舊樹脂必須從樹脂容器中移去，樹脂容器內(nèi)部清潔無雜質(zhì)。</span></p><p class="MsoNormal"><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">　　拋光樹脂一般用于超純水處理系統(tǒng)末端，來保證系統(tǒng)出水水質(zhì)維持用水標(biāo)準(zhǔn)。出水水質(zhì)都能達到</span><span lang="EN-US">18</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">兆歐以上，以及對</span><span lang="EN-US">TOC</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">、</span><span lang="EN-US">SIO2</span><span style="FONT-FAMILY: 宋體; mso-ascii-font-family: Calibri; mso-hansi-font-family: Calibri">都有一定的控制能力。<span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><o:p> </o:p></span></span></span></span></p><h2 style="BACKGROUND: white; TEXT-ALIGN: center; MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan" align="center"><span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><o:p> </o:p></span></h2><h2 style="BACKGROUND: white; TEXT-ALIGN: center; MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan" align="center"><span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><o:p> </o:p></span></h2><h2 style="BACKGROUND: white; TEXT-ALIGN: center; MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan" align="center"><span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><o:p> </o:p></span></h2><h2 style="BACKGROUND: white; TEXT-ALIGN: center; MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan" align="center"><span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><o:p> </o:p></span></h2><h2 style="BACKGROUND: white; TEXT-ALIGN: center; MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan" align="center"><span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><o:p> </o:p></span></h2><h2 style="BACKGROUND: white; TEXT-ALIGN: center; MARGIN: 0cm 0cm 0pt; mso-pagination: widow-orphan" align="center"><span lang="EN-US" style="FONT-SIZE: 13.5pt; FONT-FAMILY: 微軟雅黑; BACKGROUND: white; FONT-WEIGHT: normal; COLOR: #431553; mso-bidi-font-family: 微軟雅黑"><o:p> </o:p></span></h2><p class="MsoNormal"><span lang="EN-US"><o:p> </o:p></span></p><p>核級拋光樹脂的制成與水處理影響離子交換樹脂可以根據(jù)需要，制成粉狀、不規(guī)則顆?；蚯驙?。水處理工藝中使用的離子交換樹脂即是球狀的。由于球狀樹脂制造簡單，在采用懸浮聚合時，可以直接制成球形。在體積相同的情況下，球狀樹脂所具有的表面積大，有利于提高交換能力。</p><p><br/></p><p></p><p>離子交換樹脂</p><p>　　使用球狀樹脂，充填性好、阻力均勻，樹脂層各處的流量會較均勻。而且水通過球狀樹脂層的壓力損失小，樹脂的磨損也小。樹脂成球狀的百分率通常用圓球率表示，即樹脂呈球狀顆粒占顆?？倲?shù)的百分率。一般要求圓球率在90以上。</p><p></p><p>離子交換樹脂</p><p><span><strong><span>　　</span>離子交換樹脂使用后顏色變深的說明</strong></span></p><p>　　離子交換樹脂是一種半透明或透明的球狀物。依其組成的不同，其顏色也不一樣。苯乙烯系樹脂均呈黃色;丙烯酸系樹脂有的為無色透明，有的則呈乳白色。一般講，交聯(lián)劑多，原料中雜質(zhì)多，制出的樹脂顏色則深。離子交換樹脂在使用一般時間后，由于水中鐵或有機物的污染，顏色會變深。失效的離子交換樹脂的顏色，比再生好后的樹脂的顏色要稍深一些。因此，有時候從樹脂顏色的變化上，可以間接看出樹脂的“失效"程度。</p><p></p><p>離子交換樹脂</p><p><span><strong><span>　　</span>離子交換樹脂的粒度及均勻性對水處理影響</strong></span></p><p>　　樹脂粒度的大小，對水處理工藝有較大的影響。樹脂粒度過大，離子交換速度則會減慢;樹脂粒度過小，又會使水通過樹脂層的壓力損失增大。樹脂的粒度應(yīng)均勻，否則，由于小顆粒樹脂堵塞了大顆粒樹脂間的孔隙，水流會不均并使阻力增大。另外，樹脂粒度不均勻也會使反洗操作不易控制;反洗流速過大，會沖掉小顆粒樹脂；而反洗流速過小，又不能松動大顆粒樹脂，使反洗效果變差。通常，化學(xué)水處理使用的樹脂粒度應(yīng)以20～40目為宜。</p> <div class="sgycmmqqs" id="news_sx"><li id="sgycmmqqs" 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